Many strong motion records show that under the strong seismic vibration of, the torsional disfigurement of building structures is a common and serious damage. At present, there are no special sensors for measuring seismic rotation in the world. Most of the experts obtain rotational components through observing deformation, theoretical analysis and calculation. The theory of elastic wave and source dynamics also prove the conclusion that the surface of the earth will rotate when an earthquake occurs. Based on a large number of investigations and experiments, a rotational acceleration sensor was developed for the observation of the rotational component of strong ground motions. This acceleration sensor is a double-pendulum passive servo large-damped seismic rotational acceleration sensor with the moving coil transducer. When an earthquake occurs, the seismic rotational acceleration acts on the bottom plate at the same time. The magnetic circuit system and the middle shaft fixedly connected to the bottom plate follow the bottom plate synchronous vibration, and the moving part composed of the mass ring, the swing frame and the moving ring produces relative corners to the central axis. The two working coils mounted on the two pendulums produce the same relative motion with respect to the magnetic gaps of the two magnetic circuits. Both working coils at this time generate an induced electromotive force by cutting magnetic lines of force in the respective magnetic gaps. The generated electromotive forces are respectively input to respective passive servo large damper dynamic ring transducer circuits and angular acceleration adjusting circuits, and the signals are simultaneously input to the synthesizing circuit after conditioning. Finally, the composite circuit outputs a voltage signal proportional to the seismic rotational acceleration to form a seismic rotational acceleration sensor. The paper presents the basic principles of the rotational acceleration sensor, including its mechanical structure diagram, circuit schematic diagram and mathematical models. The differential equation of motion and its circuit equation are derived to obtain the expressions of the main technical specifications, such as the damping ratio and sensitivity. The calculation shows that when the damping ratio is much larger than 1, the output voltage of the passive servo large damping dynamic coil transducer circuit is proportional to the ground rotation acceleration, and the frequency characteristic of bandpass is wider when the damping ratio is larger. Based on the calibration test, the dynamic range is greater than or equal to 100dB and the linearity error is less than 0.05%. The amplitude-frequency characteristics, the phase-frequency characteristics and their corresponding curves of the passive servo rotational acceleration sensor are acquired through the calculations. Based on the accurate measurement of the micro-vibration of the precision rotating vibration equipment, the desired result is obtained. The measured data are presented in the paper, which verify the correctness of the calculation result. The passive servo large damping rotational acceleration sensor has simple circuit design, convenient operation and high resolution, and can be widely applied to seismic acceleration measurement of earthquake or structure. 相似文献
Due to their structural diversity and variety of biological activities, marine natural products have been the subject of extensive study. These compounds, especially phospholipid polycyclic aromatic hydrocarbons, have a wide range of pharmacological applications, including embedded DNA and central nervous system, anti-tumor, anti-virus, anti-parasite, anti-bacterial, and antithrombotic effects. Unfortunately, the insufficient drug sources have limited the development of these compounds. In this study, we isolated salinpostin compounds from a fermentation solution of marine-derived Salinospora sp., which has a common bicyclic enol-phosphotriester core framework, as well as potent and selective antimalarial activities against P. falciparum with EC_(50)=50 nmolL~(-1). The chemical synthesis of these compounds in greater quantities is necessary for their use in bioactivity studies. Thus we explored a short route with high yields and mild reaction conditions, which can generate combinatorial libraries for drug discovery and lead optimization. We developed a new total synthesis method for six cyclic enol-phosphotriester salinipotin compounds and their diastereomers. For the total synthesis of cyclipostin P, we prepared cyclic enol-phosphotriester salinipostin compounds in 10 steps from a readily accessible starting material, 1,3-dihydroxyacetone, and obtained an overall yield of 1.29%. We fully characterized these compounds by proton nuclear magnetic resonance(~1H-NMR), carbon-13 NMR(~(13)C-NMR), and high-resolution mass spectrometry(HRMS) analyses, and found they coincide absolutely with the same compounds reported previously. 相似文献
The transfer and evolution of stress among rock blocks directly change the void ratios of crushed rock masses and affect the flow of methane in coal mine gobs. In this study, a Lagrange framework and a discrete element method, along with the soft-sphere model and EDEM numerical software, were used. The compaction processes of rock blocks with diameters of 0.6, 0.8, and 1.0 m were simulated with the degrees of compression set at 0%, 5%, 10%, 15%, 20%, and 25%. This study examines the influence of stress on void ratios of compacted crushed rock masses in coal mine gobs. The results showed that stress was mainly transmitted downward through strong force chains. As the degree of compression increased, the strong force chains extended downward, which resulted in the stress at the upper rock mass to become significantly higher than that at the lower rock mass. It was determined that under different degrees of compression, the rock mass of coal mine gobs could be divided, from the bottom to the top, into a lower insufficient compression zone (ICZ) and an upper sufficient compression zone (SCZ). From bottom to top, the void ratios in the ICZ sharply decreased and those in the SCZ slowly decreased. Void ratios in the ICZ were 1.2–1.7 times higher than those in the SCZ.